Benzoyl Chloride

Benzoyl Chloride

CAS Number: 98‑88‑4

Synonyms: Benzoyl chloride; Benzoic acid chloride; α‑Chlorobenzaldehyde; Benzenecarbonyl chloride

Chemical Formula:C₇H₅ClO

Product Introduction

Colorless to slightly yellow, fuming liquid with a sharp, pungent odor. It’s a reactive acyl chloride used extensively in acylation (e.g., benzoylation), and as a precursor for benzoyl peroxide, benzophenones, dyes, fragrance chemicals, pharmaceuticals, and resins

Physical & Chemical Properties

Property Value
Appearance Colorless to pale yellow liquid (fuming in moist air)
Density @ 20 °C 1.21 g/cm³
Melting Point ~–1 °C
Boiling Point ~197–198 °C @ 101 kPa
Flash Point ~72 °C (HFP)
Vapor Pressure @ 20 °C ≈1 mm Hg (≈0.13 kPa)
Refractive Index (n₂₀ᴅ) ~1.553–1.554
Solubility Reacts with water, alcohols, amines; soluble in ethers, chloroform
Molecular Weight 140.57 g/mol

Applications

  • Acylation reagent:Used to benzoylate alcohols, phenols, amines via Schotten–Baumann reactions.
  • Intermediate:Precursor to benzoyl peroxide (initiator), benzophenones, dyes, fragrances, pharmaceuticals.
  • Specialty uses:Employed in resin production, photographic chemicals, and was even historically used as a tear-inducing agent.
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