Tri Methylol Propane

Tri Methylol Propane

CAS Number: 77‑99‑6

Synonyms: 1,1,1‑Tris(hydroxymethyl)propane; Propylidynetrimethanol; 2‑Ethyl‑2‑(hydroxymethyl)‑1,3‑propanediol; Hexaglycerol

Chemical Formula:C₆H₁₄O₃

Product Introduction

A white, hygroscopic crystalline triol containing three primary hydroxyl groups. TMP serves as a highly reactive polyol building block, valued for enhancing flexibility, crosslink density, and weather resistance in high-performance resins.

Physical & Chemical Properties

Property Value
Appearance White to off-white flakes/crystals
Melting Point 56–58 °C
Boiling Point (2 mm Hg) ~159–161 °C
Density 1.176 g/cm³ @ 20 °C
Vapor Density ~4.8 × air
Vapor Pressure <1 mm Hg @ 20 °C
Refractive Index ~1.4850 (estimate)
Water Solubility ~0.1 g/mL (clear solution)
Log P –0.97 (estimated)
Flash Point 172 °C
Stability Stable; non-volatile; resistant to hydrolysis

Applications

  • Alkyd, polyester, saturated polyester resins & coatings:provides toughness, gloss & weather resistance
  • Polyurethane foams, elastomers & adhesives: enhances crosslinking, rigidity & thermal stability
  • Synthetic lubricants & rosin esters: used to formulate high-flash, stable lubricant base stocks
  • Radiation-curable resins/diluents: acrylated or allylated TMP used in UV-curing systems & ion-exchange resins
  • Textile/heat/stabilizer additives: functional for resins, plasticizers & PVC stabilization
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